In our area skunks are not allowed as pets although this one seems to think we are in charge of feeding it! Some people do keep skunks as pets, they can be very ferret like in behavior with the main concern in that pet skunks (and all skunks) are nocturnal. As well an exotic pet, like a skunk, should never be caught wild (in most cases this is illegal) rather they should be purchased from a breeder, or adopted from a rescue group.
Read more about the Care for Pet Skunks - click here.
Read more about Skunks in General - click here.